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Add Exchange Account as Secondary to Existing PST?

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Hello: I use a POP3 account as the primary account in Outlook 2010 (32-bit) using PST storage. There are also numerous other POP accounts connected in this profile -- everything works just great. In addition, Outlook syncs to my iPhone, which must remain unaffected.

I now have a need to collaborate with someone outside my company using an Exchange account. This is for: Email, Calendar, and Contacts. My default POP3 account and my .PST data store MUST remain as the defaults in my profile...

Add Exchange Account as Secondary to Existing PST?

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